羧酸經過重氮甲烷處理得到多一個碳的同系物的反應。
反應機理
反應實例
參考文獻
- Arndt, F.; Eistert, B. Ber. 1935, 68, 200-208. Fritz Arndt (1885-1969) was born in?Hamburg, Germany. He discovered the Arndt-Eistert homologation at the University?of Breslau where he extensively investigated the synthesis of diazomethane and its reactions?with aldehydes, ketones, and acid chlorides. Fritz Arndt’s chain-smoking of?cigars ensured that his presence in the laboratories was always well advertised. Bernd?Eistert (1902-1978), born in Ohlau, Silesia, was Arndt’s Ph.D. student. Eistert later?joined I. G. Farbenindustrie, which became BASF after the Allies broke up the conglomerate?following WWII.
Fritz Arndt (1885-1969) 出生于德國漢堡。他在布雷斯勞大學任教期間發現了Arndt-Eister同系化反應，在這期間他主要研究重氮甲烷的合成以及重氮甲烷和醛酮及酰氯的反應。?另外有趣的是Fritz Arndt廣為人知的形象是一個做實驗的老煙鬼。Bernd?Eistert (1902-1978), 出生于Ohlau, Silesia，是Arndt的?Ph.D.學生。他后來進入了法本化學工業股份公司（二戰同盟國勝利后被重組為巴斯夫）工作。
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編譯自：J.J. Li, Name Reactions: A Collection of Detailed Mechanisms and Synthetic Applications, ?Arndt–Eistert homologation，page10-11.
